The Perfect m-Coloring with matrix A = [aij ]i, j2f1, , , , ,mg of a graph G = (V, E) with f1,,,, ,mg color is a vertex Coloring of G with m-color so that the number of vertices in color j adjacent to a , xed vertex in color i is aij, independent of the choice of vertex in color i. The matrix A = [aij ]i, j2f1, , , , ,mg is called the parameter matrix. We study the Perfect 4-Colorings of the 3-regular graphs of order at most 8, that is, we determine a list of all color parameter matrices corresponding to Perfect 4-Colorings of 3-regular graphs of orders 4, 6, and 8.